Berlin 2018 – wissenschaftliches Programm
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CPP: Fachverband Chemische Physik und Polymerphysik
CPP 80: Organic Thin Films, Organic-Inorganic Interfaces: Session II (joint session DS/CPP)
CPP 80.3: Vortrag
Freitag, 16. März 2018, 10:00–10:15, H 0111
Comparative in-situ studies of Au sputter growth on homo and di-block co-polymer — •Pallavi Pandit1, Matthias Schwartzkopf1, Andre Rothkirch1, Bjoern Fricke1, Marc Gensch1, Alexander Hinz2, Oleksandr Polonskyi2, Thomas Strunskus2, Simon Schaper3, Franziska C. Löhrer3, Volker Körstgens3, Franz Faupel2, Peter Müller-Buschbaum3, and Stephan V. Roth1,4 — 1DESY, Notkestr. 85, D-22607 Hamburg — 2CAU zu Kiel, LS Materialverbunde, 24143 Kiel — 3Physik-Department, LS Funktionelle Materialien, 85748 Garching — 4KTH, Teknikringen 56-58, SE-100 44 Stockholm
Nanostructured gold (Au) attracts great technological interest and it is a promising candidate for functional, optical and electronic applications. A tailored metal nanoparticle-polymer interface improves the functionality of the system; attributed to the polymer-metal interactions, which are dominated by their interfacial interactions. Sputter deposition technique has been used for depositing metallic layer of few nanometer thicknesses in a controlled fashion on polymer surfaces [1]. To this end, we have investigated the morphological changes occurring at the metal-polymer interface during deposition using GISAXS and GIWAXS [2]. Optical properties of the system have also been studied in-situ and are correlated with the morphological properties of the gold nanocluster on polystyrene, polymethelmethacrlate and the corresponding di-block co-polymer. [1] Schwartzkopf et al., ACS Appl. Mater. Interfaces 9, 5629 (2017). [2] Schwartzkopf et al., ACS Appl. Mater. Interfaces 7, 13547 (2015).