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Berlin 2018 – wissenschaftliches Programm

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HL: Fachverband Halbleiterphysik

HL 54: Organic semiconductors

HL 54.4: Vortrag

Freitag, 16. März 2018, 10:15–10:30, EW 203

Design of high mobility molecular organic semiconductorsPascal Friederich1, Franz Symalla1, Velimir Meded1, Vadim Rodin2, Christian Sprau1, Florian von Wrochem2, Alexander Colsmann1, Mario Ruben1, and •Wolfgang Wenzel11Karlsruher Insitut für Technologie , Karlsruhe, Germany — 2Sony Europe Ltd, Stuttgart, Germany

Small-molecule organic semiconductors are used in a wide spectrum of applications, ranging from organic light emitting diodes to organic photovoltaics. A number of factors determine mobility, such as molecular packing, electronic structure, dipole moment and polarizability. Presently, quantitative ab-initio models to assess the influence of these molecule-dependent properties, including the influence of dopants, are lacking. Here, we present a multi-scale model, which provides an accurate prediction of experimental data over ten orders of magnitude in mobility and demonstrate the de novo designg of a novel organic semicodunctor with improved mobility. The availability of first-principles based models to compute key performance characteristics of organic semiconductors may enable in-silico screening of numerous chemical compounds for the development of highly efficient opto-electronic devices.

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