Berlin 2018 – scientific programme
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KFM: Fachverband Kristalline Festkörper und deren Mikrostruktur
KFM 27: Postersession KFM
KFM 27.12: Poster
Thursday, March 15, 2018, 15:00–17:00, Poster E
Surface acoustic wave propagation in monoclinic ferroelectric phases in strained K0.7Na0.3NbO3 thin films — •Jutta Schwarzkopf1, Leonard von Helden1, Sijia Liang2, Roger Wördenweber2, and Martin Schmidbauer1 — 1Leibniz Institute for Crystal Growth, Max-Born-Str. 2, Berlin, Germany — 2Peter Grünberg Institute, Forschungszentrum Jülich, Jülich, Germany
Formation of ferroelectric phases with monoclinic symmetry is expected to result in enhanced piezoelectric properties. Together with high coupling coefficients, this feature can be exploited for thin film surface acoustic wave (SAW) devices. KxNa1−xNbO3 represents a suitable material system that does not only provide high coupling coefficients. In addition, monoclinic phases can be stabilized in thin films by applying anisotropic epitaxial strain. Though as known from previous studies [1], the formation of the monoclinic phase crucially depends on the incorporated lattice strain. In this work, 30 nm K0.7Na0.3NbO3 films were grown epitaxially on (110) TbScO3 and (110) GdScO3 substrates by metal-organic chemical vapor deposition. The films exhibit a compressive strain state with pseudocubic (001)pc surface orientation and periodically arranged ferroelectric stripe domains. Piezoresponse force microscopy and x-ray diffraction reveal a domain periodicity of 40 − 50 nm and domains walls that proceed along the [112] or [112] directions of the orthorhombic substrates. These films were used for SAW experiments. Differences in SAW propagation will be discussed with regard to the symmetry of different monoclinic phases.
[1] J. Schwarzkopf et al., Front. Mater. 4, 26 (2017)