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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 17: Poster Session I

CPP 17.37: Poster

Montag, 1. April 2019, 17:30–19:30, Poster B1

Analysis of metal nanostructure evolution on polymer surfaces by in-situ GISAXS during sputter deposition — •Valentin Munteanu¹, Simon J. Schaper¹, Volker Körstgens¹, Matthias Schwartzkopf², Pallavi Pandit², Alexander Hinz³, Oleksandr Polonskyi³, Thomas Strunskus³, Franz Faupel³, Stephan V. Roth⁴, and Peter Müller-Buschbaum¹ — ¹TU München, Physik-Department, LS Funktionelle Materialien, 85748 Garching — ²DESY, 22607 Hamburg — ³CAU zu Kiel, Institut für Materialwissenschaft, LS Materialverbunde, 24143 Kiel — ⁴KTH, Department of Fibre and Polymer Technology, SE-100 44 Stockholm, Sweden

A good understanding of the fabrication process of reproducible functional metal-polymer interfaces is of high importance for their use in organic electronics. Sputter deposition offers the ability to precisely control and tailor the fabrication of metal-polymer interfaces. During sputter deposition, the evolution of the metallic layer morphology is monitored in-situ with time-resolved grazing-incidence small-angle X-ray scattering (GISAXS). The resulting in-situ scattering data is processed and analyzed using the DPDAK software package. By fitting the processed data, structure parameters can be extracted whose temporal evolution reveals the mode of metal growth on polymer surfaces. Simulations with BornAgain lead to a deeper understanding of the growth mechanism of sputter deposited metal-polymer interfaces.