Regensburg 2019 – scientific programme

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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 39: Focus: Controlling Phase Formation Dynamics in Solution Processed Semiconductors - organized by Christoph Brabec, Jens Harting and Hans-Joachim Egelhaaf

CPP 39.8: Talk

Wednesday, April 3, 2019, 17:45–18:00, H14

Controlling Aggregate Formation in Conjugated Polymers by Spin-Coating Below the Critical Temperature of the Disorder Order Transition — •Anna Köhler — Soft Matter Optoelectronics and Bayreuth Institute of Macromolecular Research, University of Bayreuth, Germany

Aggregates, that is short-ranged ordered moieties in the solid-state of p-conjugated polymers, play an important role in the photophysics and performance of various optoelectronic devices. We have previously shown that many polymers change from a disordered to a more ordered conformation when cooling a solution below a characteristic critical temperature Tc. Using in situ time-resolved absorption spectroscopy on a range of semiconducting polymers including P3HT, PFO, PCPDTBT, and PCE11 (PffBT4T-2OD), we show that spincoating at a temperature below Tc can enhance the formation of aggregates with strong intra-chain coupling. An analysis of their time-resolved spectra indicates that the formation of nuclei in the initial stages of film formation for substrates held below Tc seems responsible for this. We observe that the growth rate of the aggregates is thermally activated with an energy of 310 meV, which is much more than that of the solvent viscosity (100 meV). From this we conclude that the rate controlling step is the planarization of a chain that is associated with its attachment to a nucleation center. The success of our approach for the rather dynamic deposition method of spin-coating holds promise for other solution-based deposition methods.