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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 59: Composites and Functional Polymer Hybrids

CPP 59.7: Vortrag

Donnerstag, 4. April 2019, 17:00–17:15, H8

Rigid Amorphous Phase in Polymer Nanocomposites as Revealed by Dielectric Spectroscopy and Fast Scanning Calorimetry — •Paulina Szymoniak and Andreas Schönhals — Bundesanstalt für Materialforschung und prüfung (BAM), Berlin, Germany

For inorganic/polymer nanocomposites a so-called Rigid Amorphous Phase (RAF) is formed in the interfacial region by adsorption of polymer segments onto the nanoparticles. The segmental dynamics of RAF is expected to be altered, as compared to the pure matrix, which might percolate to the entire system, affecting the overall nanocomposite properties. A combination of two relaxation spectroscopy techniques (Broadband Dielectric Spectroscopy (BDS) and Temperature Modulated DSC (TMDSC)) as well as Fast Scanning Calorimetry (FSC) were employed to investigate the structure and molecular mobility of nanocomposites based on Epoxy and Layered Doubled Hydroxides with different nanoparticle content. First, BDS investigations proved the existence of a process, which is present only for nanocomposites, assigned to the dynamics of polymer segments within RAF. Second, the amount of RAF was quantified by analyzing the change of specific heat capacity step of nanocomposites, comparing to the pure material. Thirdly, the glass transition of nanocomposites was studied with FSC, applying high heating rates (0.5-10 kK/s). Considering that all techniques probe essentially the same molecular process, an activation plot was constructed, delivering a complete picture of the molecular mobility and structure of the polymer nanocomposites including RAF.