Dresden 2020 – scientific programme
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CPP: Fachverband Chemische Physik und Polymerphysik
CPP 24: Poster Session I
CPP 24.1: Poster
Monday, March 16, 2020, 17:30–19:30, P3
Multivalent Cation-Induced Actuation of DNA-Mediated Colloidal Superlattices — Devleena Samanta1,3, •Aysenur Iscen2, Christine R. Laramy2,3, Sasha B. Ebrahimi2,3, Katherine E. Bujold1,3, George C. Schatz1,3, and Chad A. Mirkin1,2,3 — 1Department of Chemistry — 2Department of Chemical and Biological Engineering — 3International Institute for Nanotechnology, Northwestern University, Evanston IL USA
Nanoparticles functionalized with DNA can assemble into ordered superlattices with defined crystal habits through programmable DNA “bonds”. Here, we examine the interactions of multivalent cations with these DNA bonds as a chemical approach for actuating colloidal superlattices. Multivalent cations alter DNA structure on the molecular scale, enabling the DNA “bond length” to be reversibly altered between 17 and 3 nm, ultimately leading to changes in the overall dimensions of the micron-sized superlattice. The identity, charge, and concentration of the cations each control the extent of actuation, with Ni2+ capable of inducing a remarkable >65% reversible change in crystal volume. Molecular dynamics simulations provide insight into the conformational changes in DNA structure as the bond length approaches 3 nm and show that cations that screen the negative charge on the DNA backbone more effectively cause greater crystal contraction. Taken together, the use of multivalent cations represents a powerful strategy to alter superlattice structure and stability, which can impact diverse applications through dynamic control of material properties, including the optical, magnetic, and mechanical properties.