BPCPPDYSOE21 – scientific programme
Parts | Days | Selection | Search | Updates | Downloads | Help
CPP: Fachverband Chemische Physik und Polymerphysik
CPP 14: Poster Session II - Complex Fluids and Perovskites
CPP 14.5: Poster
Tuesday, March 23, 2021, 16:30–18:30, CPPp
Multi-dimensional morphology control for PS-b-P4VP templated mesoporous iron (III) oxide thin films — •Shanshan Yin1, Wei Cao1, Qing Ji2, Yajun Cheng2, Lin Song3, Nian Li1, Christian L. Weindl1, Matthias Schwartzkopf4, Stephan V. Roth4,5, and Peter Müller-Buschbaum1,6 — 1Lehrstuhl für Funktionelle Materialien, Physik-Department, Technische Universität München, 85748 Garching, Germany — 2Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo, 315201, P. R. China — 3Northwestern Polytechnical University, Xi'an 710072, China. — 4DESY, Notkestr. 85, 22603 Hamburg, Germany — 5Department of Fibre and Polymer Technology, KTH Royal Institute of Technology, SE-100 44 Stockholm, Sweden — 6Heinz Maier-Leibnitz Zentrum (MLZ), Technische Universität München, 85748 Garching, Germany
We systematically investigate the synthesis of polystyrene-block-poly(4-vinylpyridine) templated Fe2O3 thin films by changing the solvent category (DMF or 1,4-dioxane) and the polymer-to-FeCl3 ratios. DMF/1,4-dioxane mixtures with different component ratios are also prepared for revealing the effect of the solvent selectivity on the thin film morphology. The structure transition mechanism of the thin films is explained by the preferential affinity and the small-molecule surfactant micelles theory.