BPCPPDYSOE21 – wissenschaftliches Programm

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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 8: Complex Fluids - organized by Christine M. Papadakis (Technical University of Munich, Garching) (joint session CPP/DY)

CPP 8.4: Hauptvortrag

Dienstag, 23. März 2021, 11:00–11:40, CPPb

Dynamic behaviour of anisotropic magnetic particles in suspensions — •Sofia Kantorovich — University of Vienna — Ural Federal University

Stable dispersions of magnetic colloidal particles with sizes ranging from nanometers to couple of microns have been actively studied for several decades and the interest to them seems to keep growing. Such an attention to these systems is paid because of several reasons: they are biocompatible, can be remotely controlled by external magnetic fields and new synthesis techniques enable a rich variety of particle morphologies. In classical magnetic fluids with spherical polydisperse nanoparticles, dominating dipolar interactions typically limit the structural complexity of their aggregates to linear arrangements, namely chains, rings and branched structures. In this contribution I will show, how to either alter the shape of magnetic particles or their internal structure in order to extend dramatically the topology and properties of their suspensions. In particular I will focus on magnetic cubes, magnetic Janus particles, soft magnetic colloids and magnetically anisotropic nanoparticles. I will show how lattices, branched clusters of staggered chains, compact clusters, linear chains, and non aggregated configurations can be formed and interconverted reversibly in a controlled way. I will also discuss how adding an active component to magnetically anisotropic particles leads to unique properties. The results gathered in this presentation demonstrate that fundamentally new possibilities for responsive magnetic materials can arise when we step away from conventional dipolar hard spheres.