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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 12: Poster 1

CPP 12.34: Poster

Montag, 5. September 2022, 18:00–20:00, P1

Anionic surfactant detection using polydiacetylene-based nanocomposites — •Watsapon Yimkaew¹, Christine M. Papadakis², Rakchart Traiphol³, and Nisanart Traiphol¹ — ¹Laboratory of Advanced Chromic Materials, Department of Materials Science, Faculty of Science, Chulalongkorn University, Bangkok, Thailand — ²Physics Department, Technical University of Munich, Garching, Germany — ³Laboratory of Advanced Polymer and Nanomaterials, School of Materials Science and Innovation, Faculty of Science, Mahidol University, Nakhon Pathom, Thailand

Polydiacetylenes (PDAs) are color-responsive polymers to various stimuli. The development of PDAs as anionic surfactant sensors by structural modification involved complicated and costly processes. In this study, we introduce a facile approach for preparing polydiacetylene/zinc (II) ion/zinc oxide (PDA/Zn2+/ZnO) nanocomposites utilized for anionic surfactant detection. Cationic surfactant, cetyltrimethylammonium bromide (CTAB) is incorporated into the nanocomposites via a simple mixing process to adjust their color transition behaviors. Addition of CTAB at 1 mM induces the blue-to-yellow color transition of the nanocomposites. Interestingly, the nanocomposites exhibit yellow-to-red color transition in response to sodium dodecyl sulfate (SDS). This demonstrates the ability of the nanocomposites as anionic surfactant sensors. A key mechanism of the color transition is the interaction between CTAB and SDS, which induces perturbation in the outer layers of the nanocomposites.