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Regensburg 2022 – wissenschaftliches Programm

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HL: Fachverband Halbleiterphysik

HL 30: Poster 2

HL 30.30: Poster

Donnerstag, 8. September 2022, 11:00–13:00, P3

Multi-photon induced ultrafast absorption dynamics of optical excitons in 2D inorganic-organic hybrid semiconductor — •Mohammad Adnan1,2, Rudolf Bratschitsch2, and Gaddam Vijaya Prakash11Nanophotonics Lab, Department of Physics, Indian Institute of Technology Delhi, Hauz Khas, New Delhi 110016 India — 2Institute of Physics, University of Münster, Wilhelm-Klemm-Straße 10 48149 Münster, Germany

Two-dimensional inorganic-organic (IO) hybrid semiconductors have attracted prodigious attentions due to unique crystal structural packing and tunable exciton characteristics and exhibit strong optical exciton features at room temperature due to their large exciton binding energies (200-250 meV) [1]. These optical excitons are highly sensitive to the layer thickness and demonstrate distinct excitonic behaviors from surface and bulk regions. Multi-photon absorption spectroscopy is a novel probing tool which can monitor excitons from the deeper energy levels [1]. Nonlinear one-photon (3.54 eV), two-photon (1.55 eV) and three-photon (1.21 eV) transient absorption studies have been carried out to have better understanding of hot-carrier relaxations from different lower lying exciton energy levels. Fluence-dependent studies clearly demonstrate various nonlinear effects such as hot phonon bottleneck effect, exciton-exciton annihilation and Auger processes at higher fluences [2]. The results presented here may find interesting applications in developing advanced optoelectronic devices.

1. Adnan et al., Sci. Rep., 2019, 10, 2615.

2. Adnan et al., J. Phys. Chem. C., 2021, 125, 12166.

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