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KFM: Fachverband Kristalline Festkörper und deren Mikrostruktur
KFM 4: Perovskite and Photovoltaics 1 (joint session HL/CPP/KFM)
KFM 4.3: Talk
Monday, September 5, 2022, 10:00–10:15, H34
Structural properties of (hot-)pressed MAPbI3 films revealed by detailed temperature-dependent optical analyses — •Christina Witt1, Konstantin Schötz1, Nico Leupold2, Simon Biberger1, Philipp Ramming1, Ralf Moos2, and Fabian Panzer1 — 1Soft Matter Optoelectronics, University of Bayreuth, Bayreuth 95440, Germany — 2Department of Functional Materials, University of Bayreuth, Bayreuth 95440, Germany
Halide perovskites attracted much attention in recent years, due to the remarkable increase in corresponding solar cell efficiencies. More recently, hot-pressing has emerged as attractive method for manufacturing and post-treatment of perovskite films [1, 2]. However, a detailed understanding regarding the role of temperature during hot-pressing on resulting film properties is still missing. Thus, we use temperature-dependent PL and absorption measurements of MAPbI3 thin films pressed with different temperatures and in detail analyze their optical properties. This allows us to draw conclusions about structural and optoelectronic properties, revealing that an increased temperature improves film morphology, structural and optoelectronic film properties.
[1] Witt, C. et al. Impact of Pressure and Temperature on the Compaction Dynamics and Layer Properties of Powder-Pressed Methylammonium Lead Halide Thick Films. ACS Appl. Electron. Mater. 2020, 2 (8), 2619-2628.
[2] Pourdavoud, N. et al. Room-Temperature Stimulated Emission and Lasing in Recrystallized Cesium Lead Bromide Perovskite Thin Films. Adv. Mater. 2019, 31, 1903717.