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Regensburg 2022 – wissenschaftliches Programm

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O: Fachverband Oberflächenphysik

O 19: Poster Monday: Scanning Probe Techniques 1

O 19.1: Poster

Montag, 5. September 2022, 18:00–20:00, P4

Quantifying Force and Energy in Single-Molecule MetalationKarl Rothe1, •Nicolas Néel1, Marie-Laure Bocquet2, and Jörg Kröger11Institut für Physik, Technische Universität Ilmenau, D-98693 Ilmenau, Germany — 2PASTEUR, Département de Chimie, École Normale Supérieure, PSL University, Sorbonne Université, CNRS, 75005 Paris, France

An atomic force microscope is used to determine the attractive interaction at the verge of adding a Ag atom from the probe to a single free-base phthalocyanine molecule adsorbed on Ag(111). The experimentally extracted energy for the spontaneous atom transfer can be compared to the energy profile determined by density functional theory using the nudged-elastic-band method at a defined probe-sample distance.

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