SKM 2023 – scientific programme

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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 28: Molecular Electronics and Excited State Properties (joint session CPP/TT)

CPP 28.7: Talk

Wednesday, March 29, 2023, 11:00–11:15, GÖR 226

Optically detected magnetic resonance of TADF OLED emitters — •Pascal Schady, Mona Löther, Fabian Binder, Vladimir Dyakonov, and Andreas Sperlich — Experimental Physics VI, Julius Maximilian University of Würzburg, 97074 Würzburg

Thermally activated delayed fluorescence (TADF) is an efficient triplet harvesting mechanism for organic light-emitting diodes (OLED). Molecular TADF Donor-Acceptor type emitters are limited by low reverse intersystem crossing (rISC) rates and broad spectra, making them less suitable for potential OLED devices. In contrast, so-called multiple resonance (MR) effect emitters, are very promising as they show narrowband emission, even for deep blue wavelengths. MR-TADF emitters consist mostly of planar and rigidly bound benzyl groups with boron and nitrogen substituents for HOMO and LUMO pinning. As a result, the exchange integral is small, therefore the energy gap between singlet and triplet states is low enough to efficiently populate emissive singlet states by up-converting long-lived triplet states via thermal excitation, even at room temperature. However, many MR-TADF materials, like the DABNA-series behave differently in solution or as a solid. We therefore are investigating the spin system of those emitters by optically detected magnetic resonance (ODMR) in order to shed light on spin-dependent efficiency limiting pathways and how to address them to improve future OLED devices.