SKM 2023 – scientific programme

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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 51: Hybrid and Perovskite Photovoltaics III

CPP 51.5: Talk

Thursday, March 30, 2023, 16:00–16:15, GÖR 226

Simulation of the impact of processing conditions on the perovskite film morphology — •Martin Majewski, Olivier Ronsin, and Jens Harting — Forschungszentrum Jülich GmbH, Helmholtz Institute Erlangen- Nürnberg (IEK-11), Dynamics of Complex Fluids and Interfaces, Cauerstraße 1, 91058 Erlangen, Germany

The solution-processed perovskite layer forms complex structures during drying. This morphology of the dry film heavily influences the efficiency of the final solar cell. The impact of the physical mechanisms on the morphology, like for example nucleation and evaporation rate, in a drying, crystallizing wet film is not really understood yet. Therefore a better understanding of the interplay of these phenomena is needed. We will present phase field simulations which are capable to describe the main physical processes like: evaporation, diffusion, spontaneous nucleation, crystal growth and advection, to investigate the impact of processing conditions on the final morphology of the perovskite film. Comparisons of the simulation to the theory will be presented. First simulations of drying solutions, including all physical phenomena, will be shown and compared to experiments.