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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 21: Poster II

CPP 21.41: Poster

Dienstag, 19. März 2024, 18:00–20:00, Poster E

Temperature-dependent Raman spectroscopic characterization of poly(furfuryl alcohol) — Durval Bertoldo Menezes¹, Francesco D'Amico², Thomas Sepperer³, Artur Benisek⁴, and •Maurizio Musso⁴ — ¹Instituto Federal do Triângulo Mineiro, Campus Uberlândia, 38.400-970 Uberlandia, Minas Gerais, Brazil — ²Universitat Salzburg / Fachbereich Chemie und Physik der Materialien — ³Jakob-Haringer-Strasse 2a — ⁴University of Salzburg, Department of Chemistry and Physics of Materials, Jakob-Haringer-Strasse 2a, 5020 Salzburg, Austria

Recently we employed FTIR and Resonant Raman spectroscopy to investigate the chemical constitution of the polymer polyfurfuryl alcohol (PFA) synthetizes in different ways, and appearing macroscopically different: the first one being a liquid and viscous commercial sample, the second one, produced following a thermosetting procedure, being a self-prepared solid and rigid sample.

As a continuation, we have performed a set of temperature dependent Raman spectroscopic measurements in order to study the evolution of these Raman spectra during the glass transition in thermosetted PFA, adopting the same spectral analysis previously performed by us to infer about the glass transition of the polymer poly(methyl methacrylate).

Compatible with Differential Scanning Calorimetry (DSC) data, the Raman spectral features of the thermosetted PFA changed with temperature, this spectral evolution being a clear indication of the PFA glass transition.

Keywords: glass transition; poly(furfuryl alkohol); Raman spectroscopy