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Berlin 2024 – wissenschaftliches Programm

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MA: Fachverband Magnetismus

MA 49: SrTiO3: A Versatile Material from Bulk Quantum Paraelectric to 2D Superconductor III (joint session TT/KFM/MA/O)

MA 49.4: Vortrag

Freitag, 22. März 2024, 10:15–10:30, H 0104

Confined ionic-electronic systems based on SrTiO3 — •Felix Gunkel, Marcus Wohlgemuth, Moritz L. Weber, and Regina Dittmann — Peter Gruenberg Institute, Forschungszentrum Juelich

SrTiO3 reflects a a prototype ionic-electronic oxide, in which the physical properties are significantly affected by the ionic defect structure. [Gunkel et al., APL 2020] At the same time, spatial confinement of electronic charge carries led to unexpected electronic and magnetic phenomena, including 2DEG formation, magnetoresistance and localization phenomena. Here we will discuss, how spatial confinement also affects the ion-dynamics and defect-equilibria of SrTiO3, yielding interfacial defect structures and ion-dynamics that significantly differ from the bulk. [Rose et al., Adv. Mater. (2023); Weber et al., Nature Mater., to be published (Jan 2 2024)]. New opportunities to tailor such confined ionic-electronic systems arise from synthesis advances in generating transferable, free-standing SrTiO3 sheets. These reflect ideally-confined nanosheets of SrTiO3 and can serve as model system for ionic-electronic confinement phenomena as well as template for the synthesis of functional bilayer structures. We discuss the state-of-the-art of controlled bilayer synthesis and derive the required finite-size corrections in the thermodynamic description of the defect chemistry of SrTiO3, indicating that the average reduction enthalpy of SrTiO3 can be effectively reduced via confinement.

Keywords: SrTiO3; defects; confinement phenomena

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