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Berlin 2024 – wissenschaftliches Programm

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MM: Fachverband Metall- und Materialphysik

MM 8: Interface Controlled Properties, Nanomaterials and Microstructure Design II

MM 8.5: Vortrag

Montag, 18. März 2024, 12:45–13:00, C 230

Mitigation strategies for self-detachment of nanoporous thin films — •Gideon Henkelmann1, Xinyan Wu1,2, and Jörg Weissmüller1,31Institute of Materials Physics and Technology, Hamburg University of Technology, Germany — 2Institute of Optical and Electronic Materials, Hamburg University of Technology, Germany — 3Institute of Materials Research, Materials Mechanics, Helmholtz-Zentrum Geesthacht, Germany

Experiment shows thin films of dealloyed nanoporous gold (NPG) spontaneously detaching from massive gold base layers. NPG can also densify near its external surface. This is naturally reproduced by kinetic Monte Carlo (KMC) simulations of dealloying and coarsening and so appears generic for nanoscale network materials evolving by surface diffusion. This talk focuses on how the KMC simulation manages to predict intricate physical phenomena with few and simple assumptions to the kinetics. Finally, we provide strategies to mitigate the self-detachment effect supported by both simulation and experimental results.

Keywords: thin films; dealloying; surface diffusion; nanoporous metals

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