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SYCE: Symposium Coulomb Explosion Imaging

SYCE 1: Coulomb-Explosion Imaging

SYCE 1.4: Invited Talk

Tuesday, March 12, 2024, 12:30–13:00, Paulussaal

Dynamics and control of microsolvated biomolecules studied by Coulomb explosion imaging — •Sebastian Trippel1,2 and Jochen Küpper1,2,31Center for Free-Electron Laser Science CFEL, Deutches Elektronen-Synchrotron DESY, Hamburg — 2Center for Ultrafast Imaging, Universität Hamburg — 3Department of Physics, Universität Hamburg

Microsolvated biomolecules are promising model systems to study the corresponding light-induced dynamics of molecules in solution [1]. Due to the still manageable complexity of the small clusters, atomic, molecular, and optical physics methods can be used for the analysis and characterization of their dynamics. Coulomb explosion imaging is one of those methods that can be applied to distinguish the various reaction channels present. Furthermore, it allows to determine the orientation of molecules or clusters in the gas phase [2]. In this presentation, our findings on the ionization dynamics of pyrrole-water and water-dimer will be presented. In addition, we will discuss our results on the field-free alignment of complex molecules in the gas phase using pulse shaping [3].

[1] L. He, et int. (8 authors), J. Küpper, J. Phys. Chem. Lett. 14, 10499 (2023)

[2] H. Stapelfeldt and T. Seideman, Rev. Mod. Phys. 75, 543 (2003)

[3] T. Mullins, et int. (9 authors), J. Küpper et al., Nat. Commun. 13, 1431 (2022)

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