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Regensburg 2025 – wissenschaftliches Programm

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CPP: Fachverband Chemische Physik und Polymerphysik

CPP 7: Active Matter II (joint session BP/CPP/DY)

CPP 7.6: Vortrag

Montag, 17. März 2025, 16:30–16:45, H37

Sequence-specific folding of partially active polymers — •Shibananda Das — Department of Physics, Indian Institute of Science, Bengaluru, India

Biological polymers like actin filaments and microtubules exhibit important physical properties due to their out-of-equilibrium behavior induced by ATP or GTP. In contrast, synthetic polymers rely on energy from their surrounding environment, often using local chemical, electrical, or thermal gradients to remain far from equilibrium. Theoretically, active polymers serve as minimal models for these systems, enabling systematic study of the competition between thermodynamic and active forces while they undergo conformational changes.

Using a combined analytical and numerical approach, we investigate an active polymeric chain composed of multiple self-avoiding units, representing good solvent condition in the absence of active forces. For partially active polymers without orientational constraints, we find that distribution of the active units in distinct sequences along the backbone can induce a significant collapse into folded, globular structures. Detailed analysis shows that this activity-dependent collapse is driven by a reduction in swim pressure of the monomers, linking the distribution of active forces along the polymer contour to its folded conformations.

Keywords: Active Polymers; Swim Pressure; Polymer Conformation

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