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HL: Fachverband Halbleiterphysik

HL 46: Optical Properties

HL 46.10: Talk

Thursday, March 20, 2025, 12:30–12:45, H15

Theoretical and Experimental Study of Lead Tungstate (PWO-II) Crystal Properties for Electromagnetic Calorimetry — •Ather Ahmad1, Pavel Orsich1, Valera Dormenev1, Hans-Georg Zaunick1, Kai-Thomas Brinkmann1, Simone Sanna2, Martin Becker3, and Limei Chen31II. Physikalisches Institut, Gießen, Germany — 2Institut für Theoretische Physik, Gießen, Germany — 3I. Physikalisches Institut, Gießen, Germany

Lead tungstate (PbWO4 or PWO) is widely recognized as a high-performance scintillator for electromagnetic calorimeters due to its fast response, high density, and radiation hardness. PWO scintillator material is used in several experiments, such as CMS at the LHC (CERN), and the next-generation PWO-II crystals, which are doped to enhance their properties, have been optimized for the PANDA experiment at FAIR in Darmstadt.

To gain a deeper understanding of the material’s performance, we have combined theoretical and experimental approaches to study the electronic and optical properties of PWO-II. Raman spectra and light transmission measurements were conducted on PWO-II samples and compared with results from density functional theory (DFT) calculations. In our models, we consider the crystal phases stable at room temperature, revealing characteristic differences in both Raman spectra and light transmission between these phases.

These combined efforts aim to refine the characterization of PWO-II and support the development of advanced calorimeter materials.

Keywords: PWO-II; Raman; DFT; Light Transmission; Defects

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