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O: Fachverband Oberflächenphysik

O 62: Focus Session Molecular Nanostructures on Surfaces: On-Surface Synthesis and Single-Molecule Manipulation III

Wednesday, March 19, 2025, 10:30–13:00, H24

This focus session aims to discuss recent advances in the on-surface synthesis, manipulation, characterization, and understanding of complex molecular architectures on surfaces. The interest in surface-confined molecular nanostructures emerges from their prospective applications in nanoscale (opto-) electronics, spintronics, solar cells, energy storage devices, and other fields. The bottom-up fabrication of surface-supported nanostructures can be based on molecular self-assembly utilizing non-covalent intermolecular interactions, covalent on-surface synthesis, or the direct manipulation of molecules. Molecular self-assembly usually leads to highly ordered nanostructures, controlled by non-covalent interactions, adsorbate-substrate interactions, as well as thermodynamic and kinetic factors. On-surface synthesis by covalent coupling of reactive precursors adsorbed on metallic, semiconducting, or even insulating surfaces has emerged as a powerful method that has opened new possibilities in exploring new routes towards the synthesis of complex low-dimensional nanostructures with unprecedented material properties, often via novel chemical reactions not available in conventional organic chemistry. Finally, the direct manipulation of molecules with the tip of a scanning probe microscope allows for unprecedented chemical transformations or structural modifications, as envisioned by the pioneers of nanotechnology. This focus session is intended to provide a platform for addressing current trends in these closely linked fields from various perspectives in experiment and theory.

Organized by
Sabine Wenzel (University of Marburg) and Christian Wagner (Forschungszentrum Jülich)

10:30 O 62.1 Selective On-Surface Synthesis of Isokekulene Facilitated by Strong Molecule-Substrate InteractionQitang Fan, Alexander Reichmann, Zilin Ruan, Faming Kang, Tim Naumann, Simon Werner, Olaf Kleykamp, Jose Martinez, Felix Lüpke, François C. Bocquet, Christian Kumpf, Serguei Soubatch, Jörg Sundermeyer, Peter Puschnig, F. Stefan Tautz, J. Michael Gottfried, and •Sabine Wenzel
10:45 O 62.2 On-surface synthesis and characterization of long azaacenes — •Zilin Ruan, Liping Ye, Jakob Schramm, Tim Naumann, Faming Kang, Ralf Tonner-Zech, Michael Mastalerz, and J. Michael Gottfried
11:00 O 62.3 On-surface synthesis and characterization of polyynic carbon chains — •Wenze Gao, Wei Zheng, Luye Sun, Faming Kang, Zheng Zhou, and Wei Xu
11:15 O 62.4 The odd-number cyclo[13]carbon and its dimer, cyclo[26]carbon — •Florian Albrecht, Igor Rončević, Yueze Gao, Fabian Paschke, Alberto Baiardi, Ivano Tavernelli, Shantanu Mishra, Harry L. Anderson und Leo Gross
11:30 O 62.5 Invited Talk: On-Surface Synthesis with Hydrogen Atoms — •Szymon Godlewski
12:00 O 62.6 On-Surface Synthesis of Hydrogen-Substituted γ-Graphdiyne with High Efficiency — •Faming Kang, Wei Zheng, Luye Sun, Wenze Gao, Lina Shang, Lifeng Chi, and Wei Xu
12:15 O 62.7 Tip-induced nitrene generation — •Leonard-Alexander Lieske, Aaron Oechsle, Ilias Gazizullin, Matthias Krinninger, Igor Rončević, Florian Albrecht, Leonhard Grill, Friedrich Esch, and Leo Gross
12:30 O 62.8 On-Surface Synthesis and Reactivity of Biphenylene Network on Au(788) — •Ye Liu, Yingling Zhang, Zilin Ruan, Tim Naumann, Faming Kang, Ulrich Koert, and J. Michael Gottfried
12:45 O 62.9 Incorporating Nonhexagonal Polygons into Carbon-Based Nanostructures via On-Surface Synthesis — •Dong Han, Jakob Schramm, Zilin Ruan, Tim Naumann, Konstantin Y. Amsharov, Ralf Tonner-Zech, and J. Michael Gottfried
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