Regensburg 2025 – scientific programme
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O: Fachverband Oberflächenphysik
O 81: Heterogeneous Catalysis III
O 81.1: Talk
Thursday, March 20, 2025, 10:30–10:45, H6
Cu Oxide Nanoparticles for Virus Inactivation — •Daniel Silvan Dolling1,2, Miguel Blanco Garcia1,2, Mona Kohantorabi1, Mohammad Ebrahim Haji Naghi Tehrani1,2, Jan-Christian Schober1,2, Ming-Chao Kao1,2, Jagrati Dwivedi1, Arno Jeromin1, Thomas F. Keller1, Olof Gutowski3, Dimitry V. Novikov3, Andreas Stierle1,2, and Heshmat Noei1 — 1Centre for X-ray and Nano Science CXNS, Deutsches Elektronen-Synchrotron DESY, Notkestr. 85, 22607 Hamburg, Germany — 2Fachbereich Physik, Universität Hamburg, Jungiusstraße 11, 20355 Hamburg, Germany — 3Deutsches Elektronen-Synchrotron DESY, Notkestr. 85, 22607 Hamburg, Germany
TiO2 is known to inactivate SARS-CoV-2 photocatalytically under UV light. Recently, it has been shown that Cu oxide on Titania shifts the photoactivty into the visible light region. The specific oxidation state of Cu is paramount for the photocatalyst efficiency. Here, we use single crystalline TiO2 to investigate the effects of growth conditions of Cu nanoparticles (NPs). To this cause, we employ X-ray diffraction (XRD) and scanning electron microscopy (SEM), revealing a temperature-dependent morphology. Subsequently, we analyze the short- and long-term oxidation behavior with X-ray photoelectron spectroscopy (XPS) and scanning Auger microscopy (SAM). Finally, we investigate the interaction of the NPs with asparagine amino acid using reflection-absorption infrared spectroscopy (IRRAS) and grazing-incidence small-angle scattering (GISAXS).
Keywords: TiO2; Photocatalysis; Oxidation; Nanoparticle; Growth