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Dresden 2009 – scientific programme

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O: Fachverband Oberflächenphysik

O 8: Focused Session: Epitaxial Graphene I

O 8.1: Topical Talk

Monday, March 23, 2009, 11:15–11:45, SCH 251

Atmospheric pressure graphitization of SiC: a route towards wafer-size graphene filmsK.V. Emtsev1, A. Bostwick2, K. Horn3, J. Jobst1, G.L. Kellog4, L. Ley1, J.L. McChesney2, T. Ohta4, S.A. Reshanov1, J. Röhrl1, E. Rotenberg2, A.K. Schmid5, D. Waldmann1, H.B. Weber1, and •Th. Seyller11FAU Erlangen-Nürnberg — 2Advanced Light Source, USA — 3FHI Berlin — 4Sandia National Laboratories, UAS — 5National Center for Electron Microscopy, USA

Graphene, a single monolayer of sp2-bonded carbon, is a very unique 2-dimensional electron gas system with electronic properties fundamentally different to other 2DEG systems [1]. A manifold of applications has already been suggested, which requires a uniform, ordered growth of graphene on an insulating substrate. The growth of graphene on insulating silicon carbide (SiC) surfaces by high-temperature annealing in vacuum [2] was proposed for the development of graphene-based electronics [3]. However, vacuum decomposition of SiC yields graphene layers with small grains. We have investigated the growth of graphene on SiC(0001) in an argon atmosphere [4] which produces monolayer graphene films with significantly improved morphology and carrier mobility. The new growth process establishes a method for the synthesis of graphene films on a technologically viable basis. [1] A.H. Castro Neto, et al., arXiv:0709.1163v2. [2] A. Charrier, et al., J. Appl. Phys. 92 (2002) 2479. [3] C. Berger et al., J. Phys. Chem. B 108 (2004) 19912; C. Berger, et al., Science 312 (2006) 1191. [4] K.V. Emtsev, et al., arXiv:0808.1222v1.

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